Generating PDF document

Please, wait a moment

Too much time loading?
Reload the page and try again.

CYTUVA

GIR - Equilibrium between Phases Thermodynamics Specialized Group (GETEF)

Download PDF

Contact Information

Basic Information

  • UniversityUniversidad de Valladolid
  • Center
  • DepartmentApplied Physic
  • Investigation GroupEquilibrium between Phases Thermodynamics Specialized Group (GETEF)


Description

The G.E.T.E.F. of the University of Valladolid is a Research Group created in 1994, and whose identity signs would be the following:

We are a group of specialists in the thermodynamic investigation of the equilibria between fluid and condensed phases, who have mainly worked in the study of mixtures and binary and multi-component alloys, within a General Line of work that could be summarized saying that we work in: " Thermodynamic Study of the Balances between Phases that appear in Gas, Liquid and Solid Mixtures ", and which is carried out in five major Specific Research Lines that are indicated below.

Our field of research is multidisciplinary, and covers many different facets. From the experimental point of view, we can say that we have world-renowned experience in the use of a large number of different experimental techniques: High and low temperature thermometry: Calibrated with respect to absolute reference standards. Pressure measurement and vacuum obtaining. Static and dynamic calorimetry of all kinds. Volumetric properties of substances, etc. In summary: Experimental techniques for determining the thermophysical properties of all types of materials.

From the theoretical point of view, we can also say that we have knowledge of Thermodynamics and Molecular Physics -we are professors of Thermodynamics and Statistical Physics at the UVA-, which allow us to develop microscopic models on the behavior of all kinds of complex systems. In summary, we are experts in: Thermodynamics and Statistical Physics of pure substances, mixtures and alloys. Maximum entropy methods (MaxEnt) used in the study of complex systems.

Objective
  • From the point of view of basic experimental research.- The determination -in the Group Research Laboratory, or in other national or foreign Laboratories with which we have maintained stable collaborations for more than 20 years- of the equilibria between phases: Liquid -Vapor (ELV), liquid-liquid (ELL) and solid-liquid (ESL), and of the thermodynamic equilibrium properties: Energetic (enthalpies, heat capacities, etc.) or thermal (densities, coefficients of compressibility, etc.) , and transport (viscosities, etc.), of all kinds of binary or multicomponent mixtures or alloys.
  • From the point of view of basic theoretical research.- The modeling of the experimental results obtained, and many others that appear in the literature, in order to understand the inter and intramolecular microscopic interactions that take place within the mixtures and alloys; mainly, using the DISQUAC model, in whose development we have collaborated decisively, and we are internationally recognized experts: Also, and in the longer term, apply the knowledge obtained in order to model the behavior of substances of biological and environmental interest (basic molecules that make up DNA, new fuels, etc.), or other types of new materials.
  • From the point of view of applied research.- The use of the Group's experimental resources and, in general, of all the basic research carried out to improve all kinds of processes of industrial interest (new design gasoline; prediction of the solubility of polymers from the basic units that form them, improvement of the processes for making and storing bread, ...), collaborate in reducing the polluting effects that some of these processes produce in the environment (effects of improving the change the type of solvent, or the conditions of temperature, pressure, etc., to which it is used, ...), characterize the performance of new materials, etc.
  • From the point of view of the training of researchers.- The GETEF is a research group that not only has research capacity (as justified by the more than 70 articles published in journals of recognized international prestige since its foundation), but also a trainer. This is proved by the number of students of Bachelor's, Third Cycle (within the UVA Physics Doctoral Program), and Doctorate (3 members of the Group have defended their Doctoral Thesis since 2000), who continuously join the group. Which we think is worthy of being outstanding; Well, above all, we are teachers and, as such, we must also spend time teaching our students to investigate.


Other information

Number of researchers:

4

Technological Line(s):

- Experimental sciences

Development status:

In research and development phase

Applicability of technology:

Yes

Additional Information:

RESEARCH: 
  • Experimental study of associated mixtures. Fundamentally, of molecules that contain the functional groups -O- and -OH: mixtures of alcohols + ethers, and mixtures of hydroxyethers (mainly alkoxyethanes) with hydrocarbons, alcohols and ethers. Also, mixtures of molecules that contain the functional groups -NH and -OH: mixtures of amines + alcohols, etc.
  • Experimental and theoretical study of mixtures whose excess heat capacity at constant pressure has a double minimum in its dependence on concentration (that is, systems whose: CpE has a W shape).
  • Experimental study of mixtures with pure dipole interactions. Fundamentally, of molecules formed by the functional groups -O- and -CO-: mixtures of ketones + ethers; alkyl carbonates + hydrocarbons, ethers and ketones, and mixtures of organic anhydrides with hydrocarbons. Also, mixtures of amides, nitriles, etc., with hydrocarbons, etc.
  • Use of theories based on the Functional Group Contribution Method to characterize the thermodynamic properties of mixtures and alloys. Specifically, systematic application of the DISQUAC model to justify all kinds of mixtures and balances between phases, and comparison of its benefits with UNIFAC models, etc.
  • Use of association theories to justify the thermodynamic properties and the equilibria between phases that the associated mixtures present. Systematic application of the ERAS model. Study of Flory's Theory with a view to improving the ERAS model.

Other members:

ISAIAS GARCÍA DE LA FUENTE
JUAN ANTONIO GONZALEZ LOPEZ
See more

RICARDO PARAMO VELA

Photos

Videos

Other resources

Related projects

GIR - TERMOCAL

OBJECTIVES• The TERMOCAL research group (acronym for Thermodynamics and Calibration) can place its beginning with the granting of a research grant for its implementation within the first call of the Secretary of State for Universities and Research ... Read more >

Biogas optimization for fuel improvement, energy balances in EDAR (Spanish acronym for Sewage Treatment Plant) and from micro-algae.

BIOGAS UPDATE VIA BIOLOGIC CO2 CONVERSION AND H2 INTO CH4. - Biogas has become one of the main sources of renewable energy in the EU, overtaking petrol by more than 12% for the last 15 years. Currently, the main use of biogas is the combined produ... Read more >

Ocular Pathological Anatomy Laboratory (LPO)

The Ocular Pathological Anatomy Laboratory of Valladolid’s University Institute of Applied Ophthalmology (IOBA) is a laboratory specialized in the study and diagnosis of samples belonging to eyeballs, orbit and ocular appendages. Diagnostic servi... Read more >

Efficient and sustainable preparation of synthetic, natural and biomolecular products

Our research group is specialized in the design and development of methodologies to obtain any organic molecule of interest. Lately we have focused on steroids, although we are able to prepare any compound, regardless of its nature. We work on the de... Read more >

This email will be sent to the technology and knowledge transfer office. In your case, it will also be sent to the researcher responsible for the chosen project.
Fields marked with * are mandatory.

I accept the Privacy Policy

CAPTCHA Image

Type the characters shown in the image on the left.

[ Different image ]

close